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ISO 1693:1976

Cryolite, natural and artificial — Determination of fluorine content — Modified Willard-Winter method

Sep 1, 1976

General information

90.60     Mar 5, 2026

ISO

ISO/TC 226

International Standard

71.060.50  

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Scope

Specifies the determination for natural and synthetic materials having a molar ratio sodium fluoride/aluminium trifluoride between 3 and 1,7 approximately. The principle consists in fusion of a test portion with sodium carbonate, separation of fluorine by distillation with sulphuric acid or perchloric acid. Titration with thorium nitrate solution in presence of sodium alizarinsulphonate/methylene blue as indicator. Alternatively, the thorium nitrate titration may be made using only sodium alizarinsulphonate, the end-point being*spectrophotometrically determined at 525 nm.

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PUBLISHED
ISO 1693:1976
90.60 Close of review
Mar 5, 2026

National adoptions

Cryolite, natural and artificial — Determination of fluorine content — Modified Willard-Winter method

95.99   Withdrawal of Standard

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